Without knowing all the battery details, unless it is a particularly windy place I suspect that single PV panel is barely enough for the existing batteries, and certainly wont be enough if you add a whole lot more. More panels required!
Also, since you are only running a 12V battery, you are going to have 8 strings of 6V batteries in parallel with the existing 2 volt string. Overall, that is a
very bad idea. The chance of battery problems goes up dramatically with greater number of parallel strings, and 9 is way, way too many. If one cell goes, it drags the rest of the batteries in other strings down, and it would be a nightmare trying to figure out the health of so many batteries.
EDIT: Additionally, the flooded Lead-acid batteries will have different charging requirements and voltages to the UPS batteries, so connecting them all together will likely result in the premature demise of one lot or the other.